Luminous Valentine/Relationships

Holy Empire Ruberios

 * Louis Valentin and Roy Valentin
 * Both Louis and Roy have been some of Luminous's oldest and most loyal servants in her thousands of years as a Demon Lord, with the two having both served her predating the founding of Holy Empire Ruberios. The twins thave dedicated themselves to being Luminous's body doubles within both her empire and her seat on the Demon Lord council – Louis acting as the Holy Emperor, the leader of the supposed humancentric nation and Holy Church, and Roy acting as the Demon Lord "Valentin," who "replaced" her seat within the Demon Lord council. Luminous in return has shown a strong sense of attachment to the two. This is seen when Luminous revived and resurrected them after they were killed by Hinata, stating that she refuses to allow them to die and leave her alone. Later, Luminous was noticeably upset upon hearing of Roy's permanent death and was saddened by her inability to resurrect him in time.


 * Hinata Sakaguchi
 * Luminous holds great respect for her and considers Hinata her right hand. She is very close to her, to the point that she is always worried about losing her. She holds lustful thoughts towards Hinata, having even thought to herself how grateful she was for being able to look at a naked Hinata in the hot springs; with Hinata unaware Luminous is hoping to be intimate with her.


 * Clerics of the Seven Luminaries
 * She once trusted them to ensure her country and faith were being upheld. However, they fell into corruption and angered her by trying to kill Hinata. Luminous killed half of them herself, while the other four were dealt with by others.


 * Ten Great Saints
 * A few of them know of her existence and true status. They are loyal and don't wish to anger her, having seen what she was doing to punish Veldora. As shown from her revealing her existence, the Ten Great Saints were surprised that the goddess they worship was real and in actuality a Demon Lord, however with encouragement from Hinata and Luminous herself revealing that her intent was always to protect humanity, both for their sake and the sake of the low-ranked Vampires who are dependent on them for nourishment, the Ten Great Saints quickly accepted her and the system she created using her fake religion due to it having indeed brought happiness, protection and safety for the people of the Holy Empire and humanity.

Jura Tempest Federation

 * Rimuru Tempest
 * She is confused on her feelings towards him, she is somewhat envious of how close Rimuru is to Chloe, but other than that they seem to have a mostly positive relationship. Luminous is, however, grateful that Rimuru mostly holds "that damn lizard" Veldora at bay and prevents any new rampages from happening. She was surprised Rimuru handed Veldora over to her for a beating; even Rimuru knew Veldora had it coming, and to avoid having his nation targeted again if he didn't cooperate with her.


 * Veldora Tempest
 * Veldora destroyed her original kingdom and she has never forgiven him, and all attempts to get on her good graces have ended in failure for the dragon. This may be why she set up her religion to be harsh towards monsters, so that anything that spawned from Veldora's power like Charybdis couldn't threaten her home again. This doesn't help that Veldora accidentally reveals her true name and role as a Demon Lord to her Human believers. Though she said will forgive him if he learns some manners and respect here by Rimuru.

Others

 * Chloe Aubert
 * She thinks of Chloe as her savior and has great respect for her. Luminous seems to be romantically attracted to her as well; the Manga shows Luminous cuddling the holy casket containing adult Chloe while completely naked, even if her skin fizzles on contact.


 * Ultima
 * She and Violet had some sort of rivalry. She is constantly annoyed with Ultima's shenanigans and it was stated they fought before as shown in Visions of Coleus, indicating they have some history together. As stated by Luminous after Rimuru gave Violet the name "Ultima", Violet would frequently terrorize the territories under Luminous's control and protection, thus they had frequently clashed numerous times.